News from the NNI Community - Research Advances Funded by Agencies Participating in the NNI

Researchers from The University of Texas at El Paso and the Connecticut Agricultural Experiment Station have shown that nanoplastics and per- and polyfluoroalkyl substances (PFAS) – commonly known as forever chemicals – can alter proteins found in human breast milk and infant formulas. While nanoplastics originate primarily from the degradation of larger plastic materials, like water bottles and food packaging, forever chemicals are found in various products, such as cookware and clothing.

Researchers from the U.S. Department of Energy’s SLAC National Accelerator Laboratory and Argonne National Laboratory; Stanford University; Harvard University; Columbia University; Florida State University; and the University of California, Los Angeles, have discovered new behavior in an 50-nanometer-thick two-dimensional material, which offers a promising approach to manipulating light that will be useful for devices that detect, control or emit light, collectively known as optoelectronic devices. Optoelectronic devices are used in light-emitting diodes (LEDs), optical fibers, and medical imaging. The researchers found that when oriented in a specific direction and subjected to linearly polarized terahertz radiation, an ultrathin film of tungsten ditelluride circularly polarizes the incoming light.

Researchers from the U.S. Department of Energy's Princeton Plasma Physics Laboratory and the University of Delaware have provided new insights into the variations that can occur in the atomic structure of two-dimensional materials called transition metal dichalcogenides (TMDs). The researchers found that one of the defects, which involves hydrogen, provides excess electrons. The other type of defect, called a chalcogen vacancy, is a missing atom of oxygen, sulfur, selenium, or tellurium. By shining light on the TMD, the researchers showed unexpected frequencies of light coming from the TMD, which could be explained by the movement of electrons related to the chalcogen vacancy.

Researchers from the University of Illinois Urbana-Champaign have identified how gold nanoparticles transfer charge to a connecting semiconductor and quantified how much charge is transferred using different colors of light. The researchers theorized that by using light to excite collective electronic oscillations (also called a plasmon) in gold nanoparticles, they would get a boost in charge transfer to the semiconductor material. And their study confirmed their theory.

Researchers at Michigan State University have developed a new technique that combines atomic-scale imaging with extremely short laser pulses to detect single-atom defects that manufacturers add to semiconductors to tune their electronic performance. “This is particularly relevant for components with nanoscale structures,” said Tyler Cocker, a scientist who led this study. The technique is straightforward to implement with the right equipment, he added, and his team is already applying it to atomically thin materials, such as graphene nanoribbons.

Researchers from Drexel University, California State University Northridge, and the U.S. Department of Energy’s Lawrence Berkeley National Laboratory have provided the first clear look at the chemical structure of the surface of a two-dimensional (2D) material called titanium carbide MXene. MXenes form a family of 2D materials that have shown promise for water desalination, energy storage, and electromagnetic shielding. "Getting the first atomic-scale look at their surface, using scanning tunneling microscopy, is an exciting development that will open new possibilities for controlling the material surface and enabling applications of MXenes in advanced technologies,” said Yury Gogotsi, the researcher who led this study.

Researchers from The University of Texas at Austin, Baylor University, Penn State, the University of California, Berkeley, the U.S. Department of Energy’s Lawrence Berkeley National Laboratory, and Tohoku University in Japan have developed a way to blast the molecules in plastics and other materials with a laser to break them down into their smallest parts for future reuse. The discovery, which involves laying these materials on top of two-dimensional (2D) materials and then lighting them up, has the potential to improve how we dispose of plastics that are nearly impossible to break down with today's technologies. "By harnessing these unique reactions, we can explore new pathways for transforming environmental pollutants into valuable, reusable chemicals, contributing to the development of a more sustainable and circular economy," said Yuebing Zheng, one of the researchers involved in this study.

Researchers from Purdue University and the University of Illinois Urbana-Champaign have created a process to develop ultrahigh-strength aluminum alloys that are suitable for additive manufacturing. The researchers produced the aluminum alloys by using several transition metals, including cobalt, iron, nickel and titanium. "These intermetallics have crystal structures with low symmetry and are known to be brittle at room temperature," said Anyu Shang, one of the researchers involved in this study. "But our method forms the transitional metal elements into colonies of nanoscale, intermetallics lamellae that aggregate into fine rosettes. The nanolaminated rosettes can largely suppress the brittle nature of intermetallics."

As the National Institute for Occupational Safety and Health (NIOSH) Nanotechnology Research Center (NTRC) marks its 20th anniversary, NIOSH celebrates the creative work of the Engineering Controls and Personal Protective Equipment (PPE) critical topic area, one of the ten critical nanotechnology topic areas of the NTRC. NIOSH researchers have conducted laboratory and field research to develop and implement science-based national guidance for respiratory and other PPE to protect against nanomaterial exposures. This blog post highlights major milestones and success indicators of PPE knowledge and advancements.

Researchers from the University of Illinois Urbana-Champaign and Northwestern University have developed and tested a new mathematical model to accurately simulate the effects of blood flow on the adhesion and retention of nanoparticle drug carriers. The model closely corresponded to in vitro experiments, demonstrating the impact that model-based simulations can have on nanocarrier optimization. “There have been studies using mouse models and in vitro tissue models,” said Hyunjoon Kong, one of the researchers involved in this study. “However, we have been designing nanoparticles mostly by trial and error. This is the first kind of demonstration where there is a more systematic, robust design of nanoparticles, under the guidance of physics.”